Russian Mineralogical Society
2nd International Conference "Crystallogenesis and Mineralogy"
The behaviour of fibrous zeolites at the variation of water pressure

RMS-DPI code:  2007-1-65-0
Scientific session:  Session 3. Synthesis of crystalline materials and experimental mineralogy
Author listing:  Seryotkin Yu.V., Likhacheva A.Yu., Bakakin V.V.
Principal author:  Seryotkin Yurii Vladimirovich
Language:  Russian
Abstract - Summary 
(short description):
Fibrous zeolites with common formula {Ń2R2A2} [(Si,Al)5O10] are characterized by vacancies in A-positions or their partial occupancy. Their occupation by water molecules at increase of water pressure results in the structural transformation to high-hydrated phase with enlarged volume. For ordered zeolites, the transition pressure is about 1 GPa (natrolite, scolecite) or higher (thomsonite). However, an additional hydration is possible at significantly lower water pressure. The reversibility of paranatrolie– tetranatrolite phase transformation has been found. The existence of a particular phase depends on both the cation composition and the water vapour pressure in ambient atmosphere. The problem of the reversibility of paranatrolite-tetranatrolite transformation is a key problem in understanding the genesis and nomenclature of the natrolite group zeolites, which remain debatable in several aspects.
 
RMS-DPI code:  2007-1-65-0
Proceeedings volume 
in the RMS catalogue:
 
Crystallogenesis and Mineralogy
Pages:  123-126
File of proceedings 
(PDF): 
 286 K
Status:  printed
Recieved:  01/05/2007
Accepted:  16/05/2007
Published on-line:  05/01/2008
Permanent address of publication:  http://www.minsoc.ru/2007-1-65-0/
Contact author(s):  Seryotkin, Yurii Vladimirovich

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