Transformation of the crystal structure in K1-xCsxBSi2O6 solid solutions: thermal and chemical deformation
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| RMS-DPI code: |
2010-1-172-0 |
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| Scientific session: |
F2. Mineralogical crystallography and crystal chemistry. |
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| Author listing: |
Derkacheva E.S., Bubnova R.S., Filatov S.K., Krzhizhanovskaya M.G. |
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| Principal author: |
Derkacheva Elena Sergeevna |
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| Language: |
Russian |
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Abstract - Summary
(short description): | |
The leucite-like compounds with substituted B, KBSi2O6 and CsBSi2O6, are crystallized in different space groups: I-43d č Ia-3d. In this paper we have investigated the transformation of the crystal structure in the KBSi2O6 - CsBSi2O6 series due to the isomorphous substitution of the larger cation Cs+ for the smaller cation K+. The deformation of structure of CsxK1-xBSi2O6 solid solutions x=0.0; 0.2; 0.3; 0.35; 0.375; 0.4; 0.5; 0.7; 0.8; 1.0 under cationic substitution was studied by Rietveld method. The phase transition I-43d ↔ Ia3d occurs within the composition range x=0.375-0.4. The similarity between the chemical and thermal deformation was revealed.
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| Date of presentation: |
13/10/2010 |
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| Time of presentation: |
15:40 |
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| Presentation Place: |
Mining University, Hall 1166 |
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| RMS-DPI code: |
2010-1-172-0 |
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Proceeedings volume
in the RMS catalogue: | Modern mineralogy: from theory to practice |
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| Pages: |
86-87 |
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File of proceedings
(PDF): |
316 K
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| Status: |
printed |
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| Accepted: |
14/07/2010 |
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| Published on-line: |
21/11/2010 |
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| Permanent address of publication: |
http://www.minsoc.ru/2010-1-172-0/ |
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| Contact author(s): |
Derkacheva, Elena Sergeevna |
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