Synthesis and crystal structure of the new uranyl selenate with azetidine [(CH2)3NH2]2[(UO2)2(SeO4)3(H2O)]
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| RMS-DPI code: |
2014-1-93-0 |
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| Scientific session: |
F1. Mineralogical crystallogrpaphy and crystal chemistry |
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| Author listing: |
Gurzhiy V.V., Krivovichev S.V. |
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| Principal author: |
Gurzhiy Vladislav Vladimirovich |
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| Language: |
Russian |
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Abstract - Summary
(short description): | |
Single crystals of [(CH2)3NH2]2[(UO2)2(SeO4)3(H2O)] (1) were prepared by evaporation from 2 ml aqueous solution of uranyl nitrate, azetidine and 40% selenic acid. The unit cell parameters were determined by the least squares method. Compound (1) has an orthorhombic symmetry, space group P21/c, P212121, a = 10.8940(2) Å, b = 11.1207(2) Å, c = 17.8623(3) Å, V = 2164.00(7) Å3. The crystal structure was solved by direct methods from X-ray diffraction data and refined by the least-squares techniques to R1 = 0.033 (wR2 = 0.061) for 4445 reflections with |Fo| ≥ 4σF.
Keywords: uranyl selenate, crystal structure, singlecrystal X-ray diffraction |
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| RMS-DPI code: |
2014-1-93-0 |
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File of proceedings
(PDF): |
164 K
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| Status: |
printed |
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| Recieved: |
15/06/2014 |
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| Accepted: |
31/08/2014 |
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| Published on-line: |
29/12/2015 |
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| Permanent address of publication: |
http://www.minsoc.ru/2014-1-93-0/ |
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| Contact author(s): |
Gurzhiy, Vladislav Vladimirovich |
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